40 CFR Appendix V to Part 265: Appendix V to Part 265—Examples of Potentially Incompatible Waste

Many hazardous wastes, when mixed with other waste or materials at a hazardous waste facility, can produce effects which are harmful to human health and the environment, such as (1) heat or pressure, (2) fire or explosion, (3) violent reaction, (4) toxic dusts, mists, fumes, or gases, or (5) flammable fumes or gases.

Below are examples of potentially incompatible wastes, waste components, and materials, along with the harmful consequences which result from mixing materials in one group with materials in another group. The list is intended as a guide to owners or operators of treatment, storage, and disposal facilities, and to enforcement and permit granting officials, to indicate the need for special precautions when managing these potentially incompatible waste materials or components.

This list is not intended to be exhaustive. An owner or operator must, as the regulations require, adequately analyze his wastes so that he can avoid creating uncontrolled substances or reactions of the type listed below, whether they are listed below or not.

It is possible for potentially incompatible wastes to be mixed in a way that precludes a reaction (e.g., adding acid to water rather than water to acid) or that neutralizes them (e.g., a strong acid mixed with a strong base), or that controls substances produced (e.g., by generating flammable gases in a closed tank equipped so that ignition cannot occur, and burning the gases in an incinerator).

In the lists below, the mixing of a Group A material with a Group B material may have the potential consequence as noted.

Group 1-A Group 1-B

Acetylene sludge Acid sludge

Alkaline caustic liquids Acid and water

Alkaline cleaner Battery acid

Alkaline corrosive liquids Chemical cleaners

Alkaline corrosive battery fluid Electrolyte, acid

Caustic wastewater Etching acid liquid or solvent

Lime sludge and other corrosive alkalies

Lime wastewater Pickling liquor and other corrosive acids

Lime and water Spent acid

Spent caustic Spent mixed acid

Spent sulfuric acid

Potential consequences: Heat generation; violent reaction.

Group 2-A Group 2-B

Aluminum Any waste in Group 1-A or 1-B

Beryllium

Calcium

Lithium

Magnesium

Potassium

Sodium

Zinc powder

Other reactive metals and metal hydrides

Potential consequences: Fire or explosion; generation of flammable hydrogen gas.

Group 3-A Group 3-B

Alcohols Any concentrated waste in Groups 1-A or 1-B

Water Calcium

Lithium

Metal hydrides

Potassium

SO2 Cl2, SOCl2, PCl3, CH3 SiCl3

Other water-reactive waste

Potential consequences: Fire, explosion, or heat generation; generation of flammable or toxic gases.

Group 4-A Group 4-B

Alcohols Concentrated Group 1-A or 1-B wastes

Aldehydes Group 2-A wastes

Halogenated hydrocarbons

Nitrated hydrocarbons

Unsaturated hydrocarbons

Other reactive organic compounds and solvents

Potential consequences: Fire, explosion, or violent reaction.

Group 5-A Group 5-B

Spent cyanide and sulfide solutions Group 1-B wastes

Potential consequences: Generation of toxic hydrogen cyanide or hydrogen sulfide gas.

Group 6-A Group 6-B

Chlorates Acetic acid and other organic acids

Chlorine Concentrated mineral acids

Chlorites Group 2-A wastes

Chromic acid Group 4-A wastes

Hyphochlorites Other flammable and combustible wastes

Nitrates

Nitric acid, fuming

Perchlorates

Permanganates

Peroxides

Other strong oxidizers

Potential consequences: Fire, explosion, or violent reaction.

Source: “Law, Regulations, and Guidelines for Handling of Hazardous Waste.” California Department of Health, February 1975.